Shining a Light on Solar Cell Quality: New Technique Speeds Up Development

Imagine a faster and more reliable way to assess the quality of solar cells during the manufacturing process. Researchers have developed a promising technique that utilizes light to directly evaluate a solar cell’s performance before crucial processing steps. This innovation has the potential to streamline solar cell development and production.

The Challenge: Time-Consuming Quality Checks

Developing and testing new solar cell materials can be a lengthy process:

  • Traditional Methods: Typically, researchers fabricate complete solar cells before measuring their performance using specialized equipment.
  • Time and Resource Intensive: This approach requires significant time and resources, hindering rapid development cycles.

Contactless and Efficient: Surface Photovoltage Takes Center Stage

This study introduces a new technique called contactless surface photovoltage (SPV):

  • Shining a Light: The SPV method utilizes light to directly measure the electrical response within a solar cell’s material.
  • Fast and Easy: This technique can be applied directly on the material before metallization and photolithography steps, significantly speeding up quality checks.

The Science Behind SPV: Measuring Light Sensitivity

The study delves into the scientific principles behind SPV:

  • Light Creates Voltage: When light shines on a solar cell material, it generates a tiny voltage.
  • SPV Signal Strength: The strength of the SPV signal corresponds to the material’s ability to convert light into electricity.
  • Open Circuit Voltage Connection: The SPV signal is directly related to the open-circuit voltage, a crucial parameter for solar cell performance.

Testing Dilute Nitride Compounds for Multijunction Cells

The research focuses on a specific material class:

  • Multijunction Power: Multijunction solar cells stack multiple materials to capture a broader range of sunlight, potentially leading to higher efficiencies.
  • Dilute Nitride Compounds: The study explores the potential of materials called dilute nitride compounds for use in multijunction cells.

Using SPV to Analyze Material Quality

The researchers leverage SPV to assess the quality of the grown dilute nitride materials:

  • Light Sensitivity Range: SPV spectroscopy is used to determine the range of light wavelengths that the material can absorb and convert into electricity.
  • Bandgap Measurement: By analyzing the SPV data, researchers can estimate the material’s bandgap, a critical property for solar cell efficiency.
  • Quality Comparison: The SPV signal strength of the dilute nitride materials is compared to a reference solar cell made of gallium arsenide (GaAs).

SPV Reveals Reduced Performance

The study’s findings highlight a key observation:

  • Lower SPV Signal: The dilute nitride materials exhibited a significantly weaker SPV signal compared to the reference GaAs cell.
  • Open-Circuit Voltage Connection: This weaker signal correlates with lower open-circuit voltage values measured in traditional solar cell tests.

Alternative Material Shows Promise

The research explores an alternative material composition:

  • Nitrogen-Free GaAsSb: Researchers grew solar cell structures using GaAsSb, a material similar to dilute nitride compounds but without nitrogen.
  • Tailored Light Absorption: The GaAsSb material is designed to have a similar long-wavelength light absorption range as the dilute nitride compounds.
  • Stronger SPV Signal: GaAsSb structures demonstrated a significantly stronger SPV signal compared to the dilute nitride materials.

A Brighter Future for Solar Cell Development

This research on using contactless SPV for solar cell quality control offers significant advantages:

  • Faster Development Cycles: SPV allows for rapid assessment of materials before device fabrication, accelerating development.
  • Reduced Costs: By identifying promising materials earlier, SPV can help reduce development costs associated with lengthy testing procedures.
  • Improved Solar Cell Performance: The identification of better materials like GaAsSb paves the way for the development of more efficient solar cells.

By utilizing contactless SPV, researchers are taking a significant step towards a future with faster and more efficient solar cell development, ultimately leading to more powerful and affordable solar energy solutions.

Vesselin Donchev, and Malina Milanova. Surface Photovoltage Method for Photovoltaic Quality Control of GaAs-Based Solar Cells. Coatings 2023, 13(12), 2052

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